I dont know if this is the right way, but this is how I did it...
Fill radiator - start car - wait until water in radiator drops (it will suck it into engine) - top up radiator - put cap on.
watch temp guage, when you see it peak at around 235 (on my guage anyways) it will drop back down, showing the Tstat has opened up.
Open bleeder screw until you get a decent stream. watch guage for Tstat to cycle again, open bleeder... etc
Keep your eyes on the overflow tank, top it up as necessary.
I did this 4 or 5 times, then went for a 10 mile drive & bled it again, drove to work the following day, bled it once more when I got home before I shut it off...
