1. ORGANO-METALLICS
There are three primary octane-boosting additives mixed in with gasoline: organo-metallics, ethers/alcohols and aromatics. Each one has distinct chemical properties and results (along with side-effects) on octane-boosting. Some people get these families of compounds and their effects mixed up.
First, let's look at organo-metallics which is used in the little bottles of over-the-counter octane boosters, what makes them work and how they compare. By far and large, these work on the same principle as TEL-Tetra Ethyl Lead which is the principle octane-boosting component of AvGas. For automotive OTC use, a slightly less carcinogenic MMT compound is used (methylcyclopentadienyl manganese tricarbonyl); it has pretty much the same structure as TEL, but with manganese substituted for lead. These compounds have a non-linear octane-boosting curve. The initial amounts give the most boost and adding more gives decreasing benefits. Typically you get 3-4 'points' increase with these types of additives; going from 91-octane to 91.4 octane max.
As you can imagine from the metallic content, these boosters create nasty deposits in your engine. That's why they typically include a solvent such as mineral spirits to try and dissolve the deposits. Then a lubricant such as ATF or Marvel Mystery Oil is typically added to the cocktail to help your rings slide over the deposits easier and minimize the damage. If you dyno-test a car using organo-metallics (with straight-through exhaust), you can actually collect metallic pellets coming out your tailpipe. Not a good thing to be putting into your combustion chambers no less...
